Sulfur‐Centered Radicals in Visible Light Isocyanide Photochemistry

Sulfur‐centered radicals have a key role in plethora of synthetic organic transformations, whose scope has been further expanded thanks to the possibility generate such species under visible light photocatalytic conditions. The current literature overview focuses on those transformations involving isocyanides and sulfur‐centered with aim highlight chemical space accessible, both terms complexity diversity, mechanistic rational underpinning future development methodologies.